There is usually sufficient iron in the all-in-one fertilizers like Flourish Comprehensive for most planted tanks, but if you have alot of plant density (especially lots of fast growing leafy plants) and you detect signs of iron deficiency in the plants, ie. yellowing of the entire plant, then it'll be good to dose additional iron fertilizers.
As for iron toxicity, i've only read about it affecting slower growing plants like anubias, where their leaves may take in too much iron and start displaying brown patches, but that requires alot of iron content in the water for that to happen, certainly way more than what occurs naturally in a planted tank (unless the iron was purposely overdosed at extremely high amounts).
If you see brown patches on older leaves of fast growing plants like rotala rotundifolia, then its most likely just the older leaves naturally aging and deteriorating over time... leaves on such fast growing plants tend to have relatively short lifespans anyways (hence they need to be trimmed and maintained regularly).
Bookmarks