don't think it is possible.
start with empty 0.5l tank ~ 0 psi
when co2 is transferred pressure in 0.5l increases until it is in equilibrium with 5l tank. at this point how will co2 be transferred?
unless you turn 5l tank upside down so that liquid co2 is at the valve. open valve to allow liquid co2 to flow. but how are you going to decide whether tank is filled up and not overfilled?
it is better to get refill from someone/somewhere who knows how to do it.
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