I have observed something similar in my tank, except mine is a green film which only affects where the substrate is.
From what i believe i think it is either excess nutrient(s) you dose not being used by the plants and thus setteling into the soil itself. Possibly?
Another alternative i have thought of is that it is just algae growing between the substrate and just visible at the tank edge. Possibly?
If anyone has any ideas on what it could be for sure would be appreciated Mine is only guess work...
Bookmarks