That's an interesting thought but looking at the Fire Ext in my office, the head is a spray nozzle and you almost have to change the entire head to a valve type before you can attach your regulator. I would guess the canister holds the same screw mount that could fit a valve head versus a spray head.
It may be better to see if you can get an Oxygen cylinder from the local hospital or medical supply shop like those that is used for the ambulances. Just mark it CO2 so that no one mistake it for O2.









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