Copper can be very very bad.
Our Environmental Protection Agency has started mandating the addition of strong caustics (usually sodium hydroxide or lime) to domestic water to hold the pH above 7.5 or 8. That retards the copper etching and (particularly) the leeching of lead from the solder joints.
Copper and lead are heavy-metal toxins, and they are not reactive enough to form the solid (sapphire) coating that forms on aluminum as soon as it is exposed to air. The patina (green coating) on copper and the whitish lead oxide film are just not solid enough to be really protective if the pH of the water falls below 7. [I have killed whole tanks of fish before I learned that.]
Of course the EPA mandate does a number on our fish if we let ammonium get much above zero (as in shipping). I add about a double or triple dose of "Amquel" to all shipping water in an attempt to avoid sudden deaths at the other end. YMMV.
Wright
01 760 872-3995
805 Valley West Circle
Bishop, CA 93514 USA
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