I don't think it is a matter of vitamins that causes your fish to be skittish. Rather, most likely it is the conditions you keep them in.
Discus and neon tetra aren't the bravest of fish. Is your tank an empty tank, sparsely planted, well planted etc? You could provide them with places to hide, for example pieces of driftwood.
Also fishes take time to acclimatise to new environments. So if you just bought them they might still be trying to get used to the environment.









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