Actually you don't need to change the bio-media to biohomme unless you have very high stocking density. The bio-media they give you should be sufficient for most aquarium stocking needs. The rings are actually mechanical filter medias and are supposed to be placed at the bottom tray of the filter so that when waste goes through, according to ehiem it's supposed to help "break" it into smaller particles followed by the black/blue filter mat to trap the particles. The second and top trays are where almost all the bacteria will be. I'm not sure how purigen works so i'm not able to advise on where it should be placed in the filter.
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