Yes, your Pristella were spawning. The sticky balls are their eggs, which adhere to whatever plants are present. The species is an egg scatterer so that is why you found the eggs attached to it. If you could not find the eggs the next day, the parents have eaten them. Read this link for more info with regards to this species:
http://www.seriouslyfish.com/species...la-maxillaris/
Often I find that tetras prefer to spawn early in the morning. My Black Widows did the same thing but since they were in a community tank, none of the eggs could be saved.









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