Pure distilled water will almost never have a pH of 7.. It has no buffering so the tiniest thing causes big swings. Just coming to equilibrium with the atmospheric CO2 will drop the pH to the low sixes or high fives.
Calibration solutions are solutions of buffers, or mixtures thereof, that are not wildly influenced by contaminants on the probe. Be willing to buy good ones that also give temperature coefficients.
Wright









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